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Strukturänderungen bei der Reduktion von 9‐(Diphenylmethyliden)fluoren mit Natrium‐Metall zu Schichten (R 2 O)Na ⊕ ‐verknüpfter Kohlenwasserstoff‐Dianionen
Author(s) -
Bock Hans,
Ruppert Klaus,
Herdtweck Eberhardt,
Herrmann Wolfgang A.
Publication year - 1992
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19920750607
Subject(s) - fluorene , chemistry , monoclinic crystal system , crystallography , crystal structure , metal , stereochemistry , organic chemistry , polymer
Structural Changes on Reduction of 9‐(Diphenylmethylidene)fluorene by Sodium Metal to Sheets of (R 2 O)Na⊕‐ Connected Hydrocarbon Dianions The single‐crystal structure of 9‐(diphenylmethylidene)fluorene (monoclinic, space group P 2 1 / n , Z = 4) proves a CC bond length of 135 pm and a twisting of the two Ph rings out of the methylidene‐fluorene plane by 70° and 83°. Its reduction in Et 2 O solution by a Na mirror under Ar yields dark green crystals with a metallic luster. Their structure, determined in a N 2 flow cooled to 223 K (monoclinic, space group C 2/ c , Z = 4), reveals sheets of hydrocarbon dianions, connected by sodium(diethylether) links. The Na centers are sixfold coordinated as half‐sandwiches to the fluorene benzo rings and threefold allylic to the Ph rings. In the dianion of 9‐(diphenyl‐methylidene)fluorene, the central CC bond is stretched by 13 pm to 148 pm length, and the two molecular cyanine‐like halves are twisted by 51° relative to each other. Both the contact‐ion multiple structures as well as the structural changes on twofold reduction are discussed by way of comparison with literature examples and based on semiempirical calculations.