Gas‐Phase Chemistry of Ti +  to Zn +  with Butyl Isothiocyanate | Zendy

Eller Karsten | Zendy; Akkök Semiha | Zendy; Schwarz Helmut | Zendy

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Gas‐Phase Chemistry of Ti + to Zn + with Butyl Isothiocyanate

Author(s) -

Eller Karsten,

Akkök Semiha,

Schwarz Helmut

Publication year - 1991

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19910740802

Subject(s) - chemistry , ion , metal , gas phase , isotopomers , cyanate , inorganic chemistry , medicinal chemistry , organic chemistry , molecule

Using a complete set of 2 H‐labeled isotopomers, the gas‐phase reactions of Ti + to Zn + with butyl isothio‐cyanate are studied. The main product for most of the metal ions is MHNCS + formed by an ion/dipole mechanism. Exceptions are Cr + , which yields significant amounts of H 2 and H 2 S loss, Mn + , which is the only ion that does not form MHNCS + at all but produces mainly C 2 H 4 and C 3 H 6 , and Zn + , which predominantly reacts by charge transfer.

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