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Gas‐Phase Chemistry of Ti + to Zn + with Butyl Isothiocyanate
Author(s) -
Eller Karsten,
Akkök Semiha,
Schwarz Helmut
Publication year - 1991
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19910740802
Subject(s) - chemistry , ion , metal , gas phase , isotopomers , cyanate , inorganic chemistry , medicinal chemistry , organic chemistry , molecule
Using a complete set of 2 H‐labeled isotopomers, the gas‐phase reactions of Ti + to Zn + with butyl isothio‐cyanate are studied. The main product for most of the metal ions is MHNCS + formed by an ion/dipole mechanism. Exceptions are Cr + , which yields significant amounts of H 2 and H 2 S loss, Mn + , which is the only ion that does not form MHNCS + at all but produces mainly C 2 H 4 and C 3 H 6 , and Zn + , which predominantly reacts by charge transfer.