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Syntheses and Crystal Structures of 4,5‐Dihydro‐2‐(2′‐hydroxyphenyl)oxazole‐Containing Metal Complexes
Author(s) -
Bolm Carsten,
Weickhardt Konrad,
Zehnder Margareta,
Glasmacher Dorothea
Publication year - 1991
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19910740405
Subject(s) - chemistry , oxazole , metal , crystal structure , crystallography , stereochemistry , medicinal chemistry , organic chemistry
The synthesis of the complexes 3 of various metals ligated to chiral 4,5‐dihydro‐2‐(2′‐oxidophenyl‐ϰ O )oxazoles‐ϰ N is described ( Scheme ). Three of them, i.e. 3a , 3e , and 3f containing Cu II , Zn II and Ni II , respectively, were analyzed by X‐ray diffraction studies. A series of Cu II complexes ( 6a – d ) with differently substituted dihydrooxazoles have been synthesized.