Synthese von Monomorin I, einem Spurpheromon der Pharao‐Ameise ( Monomorium pharaonis ) | Zendy

Vavrecka Mojmir | Zendy; Hesse Manfred | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthese von Monomorin I, einem Spurpheromon der Pharao‐Ameise ( Monomorium pharaonis )

Author(s) -

Vavrecka Mojmir,

Hesse Manfred

Publication year - 1991

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19910740221

Subject(s) - chemistry , epimer , pyrrolidine , stereochemistry , halogenation , yield (engineering) , organic chemistry , materials science , metallurgy

Synthesis of Monomorin I, a Trail Pheromone of the Pharao Ant ( Monomorium pharaonis ) Katalytic hydrogenation of the 4‐nitroalkanone 5 yielded the cis ‐pyrrolidine ester 6 ( Scheme ). The preparation of 5 was accomplished by ethanolysis of the nitrocyclohexanone derivative 4 . Iodination at C(α) of 6 , followed by cyclization, gave a nearly 5:6 mixture of the two C(5)‐epimers 10 / 9 of octahydroindolizine. Epimerisation of the undesired 10 to 9 and subsequent transformation of the latter gave racemic monomorine I ( 1 ; 34% yield from 5 ).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research