Synthesis and Structure of the Copper(II) Complex of a Chiral Bis(dihydrooxazole) Ligand | Zendy

Hall Jonathan | Zendy; Lehn JeanMarie | Zendy; DeCian André | Zendy; Fischer Jean | Zendy

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Synthesis and Structure of the Copper(II) Complex of a Chiral Bis(dihydrooxazole) Ligand

Author(s) -

Hall Jonathan,

Lehn JeanMarie,

DeCian André,

Fischer Jean

Publication year - 1991

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19910740103

Subject(s) - chemistry , deprotonation , copper , ligand (biochemistry) , derivative (finance) , crystal structure , stereochemistry , crystallography , ion , organic chemistry , receptor , financial economics , economics , biochemistry

The bridged bis(dihydrooxazole) compound (−)‐ 2 and its silylated derivative (−)‐ 3 have been synthesised as building blocks for chiral ligands. The complex of (−)‐ 3 with Cu II has been obtained, and its crystal structure has been determined. The Cu II ion is bound to two deprotonated ligands in a twisted tetracoordinated geometry.

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