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Stoffwechselprodukte von Mikroorganismen. 257. Mitteilung. (3 S ,5 R ,6 E ,8 E )‐Deca‐6,8‐dien‐1,3,5‐triol, ein neues Stoffwechselprodukt von Streptomyces fimbriatus (M ILLARD et B URR 1926)
Author(s) -
Niederer Daniel,
Séquin Urs,
Drautz Hannelore,
Zähner Hans
Publication year - 1990
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19900730808
Subject(s) - chemistry , metabolite , derivatization , derivative (finance) , triol , stereochemistry , silylation , chromatography , diol , high performance liquid chromatography , organic chemistry , biochemistry , financial economics , economics , catalysis
(3 S ,5 R ,6 E ,8 E )‐Deca‐6,8‐diene‐1,3,5‐triol, a New Metabolite from Streptomyces fimbriatus (M ILLARD et B URR 1926) The title compound 2 , a new C 10 ‐metabolite related to the previously found (3 S ‐8 E )‐1,3‐dihydroxydec‐8‐en‐5‐one ( 1 ), was isolated from the culture filtrate of Streptomyces fimbriatus , strain Tü 2335 by solvent extraction and chromatography. The constitution and the absolute configuration were determined by spectroscopic methods and chemical derivatization. The relative configurations were determined by NOE measurements with the silyl‐protected 3,5‐isopropylidene derivative of 2 .