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An Electrochemical Variant in the Syntheses of Exaltone® and muscone: Anodic fragmentation of α, β‐unsaturated tosylhydrazones
Author(s) -
Limacher Liviana L.,
D. Delay François,
Bédert Nicole,
Tissot Paul
Publication year - 1989
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19890720627
Subject(s) - chemistry , fragmentation (computing) , anodic oxidation , electrochemistry , anode , bicyclic molecule , stereochemistry , medicinal chemistry , ring (chemistry) , organic chemistry , electrode , computer science , operating system
Ring enlargement of bicyclo[10.3.0]pentadec‐1(12)‐en‐13‐one p ‐toluenesulfonylhydrazone into cyclopentadec‐4‐yn‐l‐one was accomplished under mild and controlled anodic oxidation conditions. The mechanism of this fragmentation is reconsidered.