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Site‐Specific, Oxidative Addition of CC Bonds by ‘Anchored’ bare Fe(I) cations prior to CH bond activation. Preliminary communication
Author(s) -
Karrass Sigurd,
Schwarz Helmut
Publication year - 1989
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19890720402
Subject(s) - chemistry , ion , oxidative phosphorylation , group (periodic table) , oxidative addition , primary (astronomy) , stereochemistry , medicinal chemistry , photochemistry , crystallography , organic chemistry , catalysis , biochemistry , physics , astronomy
Evidence is presented for the first time that ‘naked’ Fe + ions, complexed to the NH 2 group of primary amines, are capable of intramolecularly activating CC bonds in a highly specific mode without preceding CH activation.