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Die röntgenstrukturanalysen von ( E )‐ und ( Z )‐2‐Buten‐1,4‐diyl‐dithiocyanat bei 93 K
Author(s) -
Belaj Ferdinand,
Huber Stefan,
Neier Reinhard
Publication year - 1988
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19880710535
Subject(s) - chemistry , molecule , double bond , crystal structure , crystallography , stereochemistry , 1 butene , polymer chemistry , organic chemistry , catalysis
The X‐Ray Diffraction Analysis of ( E )‐ and ( Z )‐2‐Butene‐1,4‐diyl Dithiocyanate The crystal structure of the ( E )‐ and ( Z )‐2‐butene‐1,4‐diyl dithiocyanate ( 1 and 2 , respectively) which have been used as substrates for an E′ reaction, has been determined by X‐ray analysis. The SCN groups are for both molecules in an anticlinal conformation relative to the double bond. A remarkable intermoecular contact has been observed between the N‐atom of one molecule and the S‐atom of its neighbour.