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EPC syntheses from bicyclic dixoanones; (−)‐5‐epidehydrofukinone
Author(s) -
Herradón Bernardo
Publication year - 1988
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19880710505
Subject(s) - chemistry , bicyclic molecule , yeast , reduction (mathematics) , stereochemistry , medicinal chemistry , biochemistry , geometry , mathematics
(−)‐5‐Epidehydrofukinone ((−) ‐15 ) has been synthesized from (2 S ,4a S ,5 S ,8a S )‐4a,5‐dimethyl‐2‐( tert ‐butyl)‐perhydro‐4 H ‐1,3‐benzodioxan‐4‐one ( 4a ), a counpound readily available by yeast reduction of ethyl 2‐oxocyclohexanecarboxylate.