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Isolierung und Strukturaufklärung epimerer 1(5),6‐Guaiadiene aus Tolubalsam
Author(s) -
Friedel Horst Dieter,
Matusch Rudolf
Publication year - 1987
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19870700619
Subject(s) - chemistry , isomerization , stereochemistry , nuclear magnetic resonance spectroscopy , organic chemistry , catalysis
Isolation and Structure Elucidation of Epimeric 1(5,)6‐Guaiadienes from Tolubalsam Two epimeric 1(5),6‐guaiadienes, which have very similar spectroscopic properties, were isolated from tolubalsam. Their structures were elucidated by NMR spectroscopy, acid‐catalyzed isomerization of γ‐gurjunene, and Diels‐Alder reactions.