Diels‐Alder ‐Reaktionen von 2,4‐Bis{[( tert ‐butyl)dimethylsilyl]oxy}‐3‐aza‐1,3‐pentadien mit Heterodienophilen | Zendy

Ried Walter | Zendy; Reiher Uwe | Zendy; Jan W. Bats | Zendy

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Diels‐Alder ‐Reaktionen von 2,4‐Bis{[( tert ‐butyl)dimethylsilyl]oxy}‐3‐aza‐1,3‐pentadien mit Heterodienophilen

Author(s) -

Ried Walter,

Reiher Uwe,

Jan W. Bats

Publication year - 1987

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19870700504

Subject(s) - chemistry , adduct , hydrolysis , medicinal chemistry , diels–alder reaction , derivative (finance) , stereochemistry , organic chemistry , catalysis , financial economics , economics

Diels‐Alder Reactions of 2,4‐Bis{[( tert ‐Butyl)dimethylsilyl]oxy}‐3‐aza‐‐1,3‐pentadien with Heterodienophiles The 2,4‐bis{[( tert ‐butyl)dimethylsilyl]oxy}‐3‐aza‐1,3‐pentadien( 2 ) reacts via the Diels‐Alder adducts 3 , 6a‐c , and 8a , b , which cannot be isolated, giving the triazines 4 , 7a‐c , and the oxadiazines 9a , b . The hydrolysis of 4 in MeOH affords the N ‐acetyl‐acetamid derivative 5 . The formula of 9a is proven by an X‐ray‐structure analysis.

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