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Revised Structure of the Fungal Germination Self‐Inhibitor Gloeosporone
Author(s) -
Meyer Walter L.,
Schweizer W. Bernd,
Beck Albert K.,
Scheifele Werner,
Seebach Dieter,
Schreiber Stuart L.,
Kelly Sarah E.
Publication year - 1987
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19870700203
Subject(s) - chemistry , germination , fungus , enantiomer , stereochemistry , constitution , botany , biology , political science , law
Gloeosporone, the germination self‐inhibitor from the fungus Colletotrichum gloeosporioides f.sp. jussiaea , is shown by spectroscopic data and X‐ray analysis to have the constitution and relative configuration as shown in Formula 2 (either (1 S ,6 R ,12 R )‐1‐hydroxy‐6‐pentyl‐5,15‐dioxabicyclo[10.2.1]pentadecan‐4,13‐dione or its enantiomer), rather than the previously assigned constitution 1 .