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Functionalisation of saturated hydrocarbons. Part 9 . Oxidation of patchouli alcohol by the ‘gif system’: Isolation and organoleptic properties of three new ketonic derivatives
Author(s) -
Barton Derek H. R.,
Belœil JeanClaude,
Billion Annick,
Boivion Jean,
Lallemand JeanYves,
Mergui Simone
Publication year - 1987
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19870700202
Subject(s) - chemistry , organoleptic , patchouli , alcohol , organic chemistry , ketone , stereochemistry , chromatography , food science , essential oil
Oxidation of patchouli alcohol ( 1 ) using the ‘Gif system’ afforded as major isolated products three new ketonic derivatives 16–18 . The structures of these compounds were established by spectral techniques including 2D‐NMR. Ketones 16–18 display interesting organoleptic properties.