Premium
The Thermal Reactivity of 5,8α‐Epidioxy‐5α‐cholestan‐3β‐yl Acetate in Acetic Acid
Author(s) -
Fuhrer Hermann,
Rihs Grety,
Lorenc Ljubinka,
Bondarenko Lidija,
Kalvoda Jaroslav,
Mihailović Mihailo Lj.
Publication year - 1987
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19870700104
Subject(s) - chemistry , reactivity (psychology) , acetic acid , derivative (finance) , thermal decomposition , epoxide , peroxide , organic chemistry , nuclear magnetic resonance spectroscopy , hydrogen peroxide , medicinal chemistry , catalysis , medicine , alternative medicine , pathology , financial economics , economics
The thermolysis of the steroidal 5α,8β‐peroxide 1 , under acidic conditions afforded in addition to the expected 5,10:8,9‐diseco derivative 2 , the rearranged 5α,8β‐epoxide 3 , the structure of which was determined by NMR spectroscopy and X‐ray analysis.