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Nukleophile Addition von Lithiumorganylen an das N , N ‐Diethyl‐10‐(trimethylsilyl)‐1, 6‐methano[10]annulen‐2‐carboxamid
Author(s) -
Neidlein Richard,
Kramer Walter,
Wirth Wolfgang
Publication year - 1986
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19860690713
Subject(s) - annulene , chemistry , trimethylsilyl , medicinal chemistry , carboxamide , quenching (fluorescence) , stereochemistry , fluorescence , physics , quantum mechanics
Nucleophilic Addition of Lithiumorganyles to N , N ‐Diethyl‐10‐(trimethylsilyl)‐1,6‐methano[10]annulene‐2‐carboxamide Reaction of lithiumorganyles with N , N ‐diethyl‐10‐(trimethylsilyl)‐1,6‐methano[10]annulene‐2‐carboxamide followed by quenching with H 2 O or MeI yields 2,3‐dihydro derivatives of 1,6‐methano[10]annulene.