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The Absolute Configuration of β‐Bisabolol
Author(s) -
Ohloff Günther,
Giersch Wolfgang,
Näf Regula,
Delay François
Publication year - 1986
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19860690321
Subject(s) - chemistry , absolute configuration , enantioselective synthesis , stereochemistry , absolute (philosophy) , terpene , organic chemistry , catalysis , philosophy , epistemology
From bergamot oil ( Citrus bergamia RISSO), (−)‐(4 S , 8 R )‐8‐epi‐α‐bisabolol ( 2 ) and (−)‐(4 R , 8 S )‐4‐epi‐β‐bisabolol ( 3 ) were isolated. The absolute configuration of their stereoisomers 4 and 5 was established by an enantioselective synthesis starting from (−)‐( S )‐ p ‐mentha‐1,8‐dien‐4‐ol.
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