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Reaktionskinetik einer Monomolekularen Oberflächenbelegung von Germanium mit 4‐(Trichlorsilylmethyl)benzonitril mit Hilfe von FTIR‐Experimenten
Author(s) -
Calzaferri Gion,
Gori Marcel
Publication year - 1985
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19850680614
Subject(s) - benzonitrile , germanium , chemistry , attenuated total reflection , fourier transform infrared spectroscopy , kinetics , infrared , total internal reflection , analytical chemistry (journal) , infrared spectroscopy , organic chemistry , optics , silicon , materials science , optoelectronics , physics , quantum mechanics
Kinetics of Monomolecular Surface Modification of 4‐(Trichlorosilylmethyl)benzonitrile on Germanium by Means of FTIR Experiments A Fourier transform‐attenuated total internal reflection‐infrared spectroscopy (FT‐ATR‐IR) technique is described, which allows to observe the kinetics of monomolecular surface modification on materials which are feasible to total internal reflection experiments in an appropriate wavelength region. First results are reported for the reaction of 4‐(trichlorosilymethyl)benzonitrile on germanium. The reaction is slower than expected and is only completed after approximately 4 h.