Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand | Zendy

Caron Aimery | Zendy; Guilhelm Jean | Zendy; Riche Claude | Zendy; Pascard Claudine | Zendy; Alpha Béatrice | Zendy; Lehn JeanMarie | Zendy; RodriguezUbis JuanCarlos | Zendy

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Photoactive Cryptands. Crystal Structure of the Sodium Cryptate of the Tris(phenanthroline) Macrobicyclic Ligand

Author(s) -

Caron Aimery,

Guilhelm Jean,

Riche Claude,

Pascard Claudine,

Alpha Béatrice,

Lehn JeanMarie,

RodriguezUbis JuanCarlos

Publication year - 1985

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19850680609

Subject(s) - chemistry , cryptand , ligand (biochemistry) , tris , phenanthroline , crystal structure , enantiomer , crystallography , sodium , stereochemistry , organic chemistry , ion , biochemistry , receptor

The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl 3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na + cation being contained in the molecular cavity of 1 and coordinated to all eight N‐atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms.

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