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Makrocyclische Ionophore beruhend auf oligomeren Terephthaldiamiden mit von Gastmolekülen abhängiger Selektivität
Author(s) -
Behm Felix,
Simon Wilhelm,
Müller Walter M.,
Vögtle Fritz
Publication year - 1985
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19850680416
Subject(s) - chemistry , ionophore , selectivity , amide , molecule , polymer chemistry , medicinal chemistry , stereochemistry , membrane , organic chemistry , catalysis , biochemistry
Macrocyclic Oligolactams Based on Terephthalic Acid as Ionophores with Selectivity Depending on Included Guest Molecules Macrocyclic 20‐ to 60‐membered oligolactam hosts exhibit ion selectivities in poly(vinyl chloride) membranes which depend on the ring size and on the substituents of the amide N‐atoms. The selectivity may be changed by loading the macrocyclic host with CHCl 3 as guest molecule.