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Propellanes. Part LXXX. Baeyer ‐ Villiger Oxidation of [4.3.3]Propellane‐8,11‐dione
Author(s) -
Ashkenazi Pnina,
Kapon Moshe,
Piantini Umberto,
Philipsborn Wolfgang Von,
Ginsburg David
Publication year - 1985
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19850680313
Subject(s) - chemistry , propellane , baeyer–villiger oxidation , lactone , nuclear magnetic resonance spectroscopy , stereochemistry , organic chemistry , medicinal chemistry , bicyclic molecule , catalysis
Oxidation of the title compound with m ‐chloroperbenzoic acid affords a keto‐lactone, two bis‐lactones and a bis‐spirolactone, in varying amounts depending upon the reaction conditions. The structures were established by means of X‐ray diffraction, 1 H‐ and 13 C‐NMR spectroscopy.