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Stereoselective glycosylation of Alcohols and Silyl Ethers Using Glycosyl Fluorides and Boron Trifluoride Etherate
Author(s) -
Kunz Horst,
Sager Wilfried
Publication year - 1985
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19850680134
Subject(s) - boron trifluoride , chemistry , stereoselectivity , glycosyl , acetal , silylation , pyranose , glycosylation , furanose , organic chemistry , alkyl , medicinal chemistry , catalysis , biochemistry , ring (chemistry)
The stereoselective glycosylation of alcohols and their silyl ethers has been achieved using O ‐alkyl‐, O ‐acyl‐, and acetal‐protected glycosyl fluorides of the pyranose and furanose series and boron trifluoride etherate in CH 2 Cl 2 .