Planarisation of Tetracoordinate Carbon Atom. A Further Route ot (all‐ cis )‐[5.5.5.5]Fenestrane | Zendy

Luyten Marcel | Zendy; Keese Reinhart | Zendy

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Planarisation of Tetracoordinate Carbon Atom. A Further Route ot (all‐ cis )‐[5.5.5.5]Fenestrane

Author(s) -

Luyten Marcel,

Keese Reinhart

Publication year - 1984

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19840670829

Subject(s) - chemistry , tetracoordinate , deoxygenation , dicyclopentadiene , atom (system on chip) , carbon fibers , carbon atom , catalysis , stereochemistry , medicinal chemistry , organic chemistry , ring (chemistry) , polymerization , polymer , computer graphics (images) , materials science , composite number , computer science , composite material , planar , embedded system

The synthesis of (all‐ cis )‐[5.5.5.5]fenestrane ( 3 ) from dicyclopentadiene is reported. Key step is the Pd‐catalyzed reductive deoxygenation of an appropriately substituted cyclooctanone, which leads to transannular C,C‐bond formation.

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