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Nukleophile Reaktionen an 2‐Phenylindolenin‐3‐onen
Author(s) -
Adam JeanMarie,
Winkler Tammo
Publication year - 1984
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19840670820
Subject(s) - chemistry , reagent , nucleophile , malonic acid , medicinal chemistry , hydrogen peroxide , nuclear magnetic resonance spectroscopy , organic chemistry , catalysis
Nucleophilic Reactions on 2‐Phenylindolenin‐3‐ones Nucleophilic reagents such as 4‐nitrophenylhydrazine, malonic acid derivatives, and hydrogen peroxide react with 2‐phenylindolenin‐3‐ones giving, in the first step, addition products to the (d) NC(2) bond. This addition can be reversible, but in most cases new rearrangement products are formed. The structure of the new compounds were elucidated by 1 H‐ and 13 C‐NMR spectroscopy.