Synthese von  N ‐(4‐Aminobutyl)‐16‐aza‐19‐nonadecanlactam und  N ‐(4‐Aminobutyl)‐17‐aza‐20‐icosanlactam (Desoxoinandenin) | Zendy

Wälchli Rudolf | Zendy; Giggisberg Armin | Zendy; Hesse Manfred | Zendy

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Synthese von N ‐(4‐Aminobutyl)‐16‐aza‐19‐nonadecanlactam und N ‐(4‐Aminobutyl)‐17‐aza‐20‐icosanlactam (Desoxoinandenin)

Author(s) -

Wälchli Rudolf,

Giggisberg Armin,

Hesse Manfred

Publication year - 1984

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19840670819

Subject(s) - chemistry , spermidine , stereochemistry , medicinal chemistry , organic chemistry , enzyme

Synthesis of N ‐(4‐Aminobutyl)‐16‐aza‐19‐nonadecanelactam and N ‐(4‐Aminobutyl)‐17‐aza‐20‐icosanelactam (Desoxoinandenine) According to Scheme 1 , the two homologous macrocyclic spermidine derivatives 12 and 23 were synthesized. Key steps in both cases were two different types of ring‐enlargement reactions. Compound 12 was identical with a degradation product of the naturally occurring spermidine alkaloids of inandenine‐type.

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