The Reaction of 4‐Hydroperoxy‐2,4,6‐trimethylcyclohexa‐2,5‐dienone with Acetaldehyde. Formatino of the Bis(peroxyacetal) | Zendy

Jefford Charles W. | Zendy; Bernardinelli Gérald | Zendy; McGoran Ernest C. | Zendy

Premium

The Reaction of 4‐Hydroperoxy‐2,4,6‐trimethylcyclohexa‐2,5‐dienone with Acetaldehyde. Formatino of the Bis(peroxyacetal)

Author(s) -

Jefford Charles W.,

Bernardinelli Gérald,

McGoran Ernest C.

Publication year - 1984

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19840670733

Subject(s) - chemistry , acetaldehyde , acetal , yield (engineering) , trimethylsilyl , trimethylsilyl trifluoromethanesulfonate , trifluoromethanesulfonate , medicinal chemistry , ether , catalysis , diethyl ether , organic chemistry , ethanol , materials science , metallurgy

The reaction of 4‐hydroperoxy‐2,4,6‐trimethylcyclohexa‐2,5‐dienone with acetaldehyde using trimethylsilyl trifluoromethanesulfonate as catalyst gives 1,1′‐bis[(1,3,5‐trimethyl‐4‐oxo‐2,5‐cyclohexadienyl) peroxy]diethyl ether ( 7 ) in 70% yield. The structure of this unusual acetal was determined by X‐ray analysis.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research