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Zum Mechanismus der Aziridinsynthese aus 2‐Azidoalkoholen und Triphenylphosphin
Author(s) -
Pöchlauer Peter,
Müller Ernst Peter,
Peringer Paul
Publication year - 1984
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19840670510
Subject(s) - chemistry , triphenylphosphine , aziridine , medicinal chemistry , imine , organic chemistry , catalysis , ring (chemistry)
On the Mechanism of the Aziridine Synthesis from 2‐Azido‐alcohols and Triphenylphosphine The reaction of selected 2‐azido‐alcohols, their pivalates, and methanesulfonates with triphenylphosphine was investigated. It is shown that the formation of aziridines from 2‐azido‐alcohols proceeds via 1,3,2λ 5 oxazaphospholidines. Furthermore, the first synthesis of the unsubstituted acenaphtene‐1,2‐imine is described.