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Absolute Configuration of Gilmaniellin
Author(s) -
Snatzke GÜNther,
Tamm Christoph
Publication year - 1984
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19840670308
Subject(s) - chemistry , absolute configuration , sign (mathematics) , couplet , absolute (philosophy) , stereochemistry , mathematical analysis , art , mathematics , poetry , literature , philosophy , epistemology
The absolute configuration of dechlorogilmaniellin ( 2 ) could be determined from its chiroptical data by applying coupled‐oscillator theory to the CD couplet around 272 nm and from the sign of its n →π * Cotton effect. Gilmaniellin ( 1 ) has the same absolute configuration.