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Synthetic routes to trace constituents of algal pheromone bouqets and other information‐imitating substances
Author(s) -
Boland Willhelm,
Mertes Karin
Publication year - 1984
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19840670230
Subject(s) - chemistry , synthon , cyclopentene , pheromone , alkylation , organic chemistry , lactone , stereochemistry , botany , catalysis , biology
Structural modifications of multifidene ( 1 ), viridiene ( 2 ) and ectocarpene ( 5 ) led to the synthesis of eleven new pheromone components or imitatin substances mostly by Grignard alkylation of cyclopentene and cycloheptadiene synthons. A new lactone α,ω dienol conversion is reported.