Structural Studies of Crystalline Pentacalent Organobismuth Compounds | Zendy

Barton Derek H. R. | Zendy; Charpiot Brigitte | Zendy; Dau Elise Tran Huu | Zendy; Motherwell William B. | Zendy; Pascard Claudine | Zendy; Pichon Clotilde | Zendy

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Structural Studies of Crystalline Pentacalent Organobismuth Compounds

Author(s) -

Barton Derek H. R.,

Charpiot Brigitte,

Dau Elise Tran Huu,

Motherwell William B.,

Pascard Claudine,

Pichon Clotilde

Publication year - 1984

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19840670227

Subject(s) - chemistry , bismuth , trigonal bipyramidal molecular geometry , lone pair , polyhedron , crystallography , trigonal crystal system , stereochemistry , ion , crystal structure , molecule , organic chemistry , geometry , mathematics

The syntheses and X‐Ray analyses of three pentavalent organobismuth compounds are described; one of these compounds has a novel diphenylbis(trifluoroacetato)‐bismuthate anion with trigonal bipyramidal geometry and a stereochemically active lone pair. Analysis of these structures together with other data from the literature allows a mapping of the reaction coordinate for bismuth polyhedra.

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