Premium
Synthesen und chemische Reaktionen neuer Chinonderivate mit 1,6‐Methano[10]annulenpartialstruktur oder ihrer Valenztautomeren
Author(s) -
Neidlein Richard,
Martin Radke Christoph
Publication year - 1983
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19830660829
Subject(s) - chemistry , annulene , hydrazone , quinone , medicinal chemistry , alkylation , nitrogen atom , chemical reduction , stereochemistry , organic chemistry , ring (chemistry) , catalysis , electrochemistry , electrode
Syntheses and Chemical Reactions of New Quinone Derivatives with 1,6‐Methano[10]annulene Fragments or their Valencetautomers The coupling of 2‐Methoxy‐1,6‐methano[10]annulene with aryldiazonium salts leads to the corresponding quinone hydrazones. These compounds undergo reduction with LiAlH 4 , condensation with hydrazines and hydrazides and alkylation at the carbonyl O‐atom or the hydrazone N‐atom.