Synthesen und chemische Reaktionen neuer Chinonderivate mit 1,6‐Methano[10]annulenpartialstruktur oder ihrer Valenztautomeren | Zendy

Neidlein Richard | Zendy; Martin Radke Christoph | Zendy

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Synthesen und chemische Reaktionen neuer Chinonderivate mit 1,6‐Methano[10]annulenpartialstruktur oder ihrer Valenztautomeren

Author(s) -

Neidlein Richard,

Martin Radke Christoph

Publication year - 1983

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19830660829

Subject(s) - chemistry , annulene , hydrazone , quinone , medicinal chemistry , alkylation , nitrogen atom , chemical reduction , stereochemistry , organic chemistry , ring (chemistry) , catalysis , electrochemistry , electrode

Syntheses and Chemical Reactions of New Quinone Derivatives with 1,6‐Methano[10]annulene Fragments or their Valencetautomers The coupling of 2‐Methoxy‐1,6‐methano[10]annulene with aryldiazonium salts leads to the corresponding quinone hydrazones. These compounds undergo reduction with LiAlH 4 , condensation with hydrazines and hydrazides and alkylation at the carbonyl O‐atom or the hydrazone N‐atom.

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