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Michael Addition of Lithio‐α‐(methyldiphenylsilyl)acetate to Cyclopentenone: A direct synthesis of (±)‐methyl jasmonate
Author(s) -
Oppolzer Wolfgang,
Guo Modao,
Baettig Kurt
Publication year - 1983
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19830660725
Subject(s) - chemistry , cyclopentenone , methyl jasmonate , alkylation , jasmonate , michael reaction , organic chemistry , methyl acetate , catalysis , biochemistry , arabidopsis , mutant , gene
Aprotic 1,4‐addition of a lithiated α‐(methyldiphenylsilyl)acetate to cyclopentenone and in situ enolate alkylation provides a direct synthesis of (±)‐methyl jasmonate (Scheme 3) .
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