Premium
Photosensitized Oxygenation of Abieta‐7,9(11)‐dien‐13β‐ol
Author(s) -
Zelnik Raymond,
Rabenhorst Ema,
Haider Akhtar,
Lauterwein Jürgen,
Wyler Hugo
Publication year - 1983
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19830660309
Subject(s) - chemistry , diterpene , oxygenation , dehydration , stereochemistry , medicine , biochemistry
Dehydration of abiet‐8‐ene‐7β, 13β‐diol (ibozol, 1 ) leads to abieta‐7,9(11)‐dien‐13β‐ol ( 2 ) which aromatizes slowly to the known abieta‐8,11,13‐triene ( 3 ). Photosensitized oxygenation of the heteroannular diene 2 yields a mixture from which three compounds were identified; abiet‐7‐ene‐9α, 11α, 13β‐triol ( 4 ), abieta‐8,11,13‐trien‐7‐one ( 5 ), and abieta‐8,11,13‐trien‐7α‐ol ( 6 ).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom