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The Structure of C‐Alkaloid‐O, a Constituent of Calabash Curare. Part 187. Papers on organic natural products
Author(s) -
Borris Robert P.,
Guggisberg Armin,
Hesse Manfred
Publication year - 1983
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19830660202
Subject(s) - chemistry , alkaloid , derivative (finance) , natural product , stereochemistry , curare , salt (chemistry) , organic chemistry , medicine , financial economics , economics , pharmacology
The structure of C‐alkaloid‐O ( 1 =his HCL‐salt) was established on the basis of spectral data and comparison with the analogous compound 2 , synthesized from a natural product of known absolute configuration. Internally consistent 13 C‐NMR. assignments are given for 1, 2 , huntrabrine methochloride (4) and its diacetate derivative 5 .