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Über die Reaktion 1,2‐disubstituierter Norbornane mit Dinatriumtetracarbonylferrat(‐II). Vorläufige Mitteilung
Author(s) -
Camenzind Hugo,
Vögeli Ulrich Christian,
Keese Reinhart
Publication year - 1983
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19830660118
Subject(s) - norbornane , chemistry , reagent , substituent , stereochemistry , medicinal chemistry , organic chemistry
Reductive elimination at 1,2 exo ‐diiodonorbornane ( 6 ) was induced by Collman's reagent. Surprisingly, 1,2 endo ‐diiodonorbornane ( 9 ) and 1‐iodo‐2 endo ‐trifluoromethylsulfonyloxy‐norbornane ( 10b ) lead only to reactions of the substituent in 2‐position. Mechanistic aspects are related to the reactions of monosubstituted iodonorbornanes with Collman's reagent.