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π‐Orbital Interactions in Möbius ‐Type Molecules as Studied by Photoelectron Spectroscopy
Author(s) -
Haselbach Edwin,
Neuhaus Louis,
Johnson Richard P.,
Houk Kendall N.,
PaddonRow Michael N.
Publication year - 1982
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19820650609
Subject(s) - chemistry , x ray photoelectron spectroscopy , molecule , molecular orbital , space (punctuation) , spectroscopy , type (biology) , computational chemistry , chemical physics , crystallography , nuclear magnetic resonance , organic chemistry , quantum mechanics , physics , linguistics , philosophy , ecology , biology
Some benzobarrelenes were studied by photoelectron (PE.) spectroscopy. The results can be interpreted by considering dominant through‐space interaction of the π‐molecular fragments in a Möbius ‐fashion, Some chemical features of the substrates are rationalized on the basis of these findings.