N, N, N ′, N ′‐Tetrabutyl‐3,6‐dioxaoctan‐dithioamid, ein ionophor mit Cd 2+ ‐Selektivität, Röntgenstrukturanalyse des Cd 2+ ‐Komplexes | Zendy

Sauter Hansjürg | Zendy; Dobler Max | Zendy

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N, N, N ′, N ′‐Tetrabutyl‐3,6‐dioxaoctan‐dithioamid, ein ionophor mit Cd 2+ ‐Selektivität, Röntgenstrukturanalyse des Cd 2+ ‐Komplexes

Author(s) -

Sauter Hansjürg,

Dobler Max

Publication year - 1982

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19820650420

Subject(s) - chemistry , ligand (biochemistry) , selectivity , medicinal chemistry , stereochemistry , ion , crystallography , catalysis , receptor , organic chemistry , biochemistry

N, N, N′,N′ ‐Tetrabutyl‐3,6‐dioxaoctan‐dithioamid, an Ionophore with Cd 2+ ‐Selectivity The CdCl 2 ‐complex of N, N, N′, N′ ‐tetrabutyl‐3, 6‐dioxaoctanedithioamide crystallizes with the composition [Ligand. Cd 2 Cl 4 ] in space group P 1 , a = 14.140, b = 10.025, c = 12.173 Å, α = 95.59°. β = 102.06°. γ = 85.50° Z = 2. Each ligand coordinates two Cd 2+ ‐ions. Adjacent cations are bridged by two Cl + ‐ions such that infinite bands along the b ‐axis are formed.

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