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N, N, N ′, N ′‐Tetrabutyl‐3,6‐dioxaoctan‐dithioamid, ein ionophor mit Cd 2+ ‐Selektivität, Röntgenstrukturanalyse des Cd 2+ ‐Komplexes
Author(s) -
Sauter Hansjürg,
Dobler Max
Publication year - 1982
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19820650420
Subject(s) - chemistry , ligand (biochemistry) , selectivity , medicinal chemistry , stereochemistry , ion , crystallography , catalysis , receptor , organic chemistry , biochemistry
N, N, N′,N′ ‐Tetrabutyl‐3,6‐dioxaoctan‐dithioamid, an Ionophore with Cd 2+ ‐Selectivity The CdCl 2 ‐complex of N, N, N′, N′ ‐tetrabutyl‐3, 6‐dioxaoctanedithioamide crystallizes with the composition [Ligand. Cd 2 Cl 4 ] in space group P 1 , a = 14.140, b = 10.025, c = 12.173 Å, α = 95.59°. β = 102.06°. γ = 85.50° Z = 2. Each ligand coordinates two Cd 2+ ‐ions. Adjacent cations are bridged by two Cl + ‐ions such that infinite bands along the b ‐axis are formed.