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Synthesis of Methyl 2‐Acetamido‐4,6‐di‐ O ‐acetyl‐3‐ S ‐acetyl‐2‐deoxy‐3‐thio‐α‐ D ‐mannopyranoside
Author(s) -
Miljković Momčilo,
Hagel Peter
Publication year - 1982
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19820650205
Subject(s) - chemistry , stereochemistry , intramolecular force , derivative (finance) , thio , methyl group , group (periodic table) , medicinal chemistry , organic chemistry , financial economics , economics
Methyl‐2‐acetamido‐4,6‐di‐ O ‐acetyl‐3‐ S ‐acetyl‐2‐deoxy‐3‐thio‐α‐D‐mannopy‐ranoside has been synthesized by conversion of methyl 2‐amino‐2‐deoxy‐4,6‐ O ‐benzylidene‐α‐D‐altropyranoside into the corresponding 3‐ O ‐methanesulfony1‐2‐ N ‐[(methylthio)thiocarbonyl]derivative followed by intramolecular displacement of the 3‐ O ‐methanesulfonyloxy group with the (methylthio)thiocarbamoyl group.