Tetrameric Cubic Structures of Two Solvated Lithium Enolates | Zendy

Amstutz René | Zendy; Bernd Schweizer W. | Zendy; Seebach Dieter | Zendy; Dunitz Jack D. | Zendy

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Tetrameric Cubic Structures of Two Solvated Lithium Enolates

Author(s) -

Amstutz René,

Bernd Schweizer W.,

Seebach Dieter,

Dunitz Jack D.

Publication year - 1981

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19810640819

Subject(s) - chemistry , cyclopentanone , lithium (medication) , tetrahydrofuran , solvent , molecule , crystallography , ion , lithium atom , atom (system on chip) , inorganic chemistry , organic chemistry , ionization , medicine , computer science , embedded system , endocrinology , catalysis

The structures of the crystalline lithium enolates derived from 3, 3‐dimethyl‐2‐butanone and from cyclopentanone have been determined by X‐ray analysis. Both structures are tetrameric aggregates based on a Li 4 O 4 ‐cube, each Li + ‐ion being additionally bonded to the O‐atom of a tetrahydrofuran solvent molecule.

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