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Ru‐Catalyzed Oxidation of Acetylenes to α‐Diketones with Iodosylbenzene
Author(s) -
Müller Paul,
Godoy José
Publication year - 1981
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19810640807
Subject(s) - chemistry , catalysis , medicinal chemistry , photochemistry , organic chemistry
Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.