Premium
Ru‐Catalyzed Oxidation of Acetylenes to α‐Diketones with Iodosylbenzene
Author(s) -
Müller Paul,
Godoy José
Publication year - 1981
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19810640807
Subject(s) - chemistry , catalysis , medicinal chemistry , photochemistry , organic chemistry
Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom