Die Produkte der Thermolyse von  N ‐(1‐Pyridinio)‐2‐nitroaniliden sind keine Triaziridine, sondern 1, 2‐Bis[(2′‐nitrophenyl)‐azoxyl]‐benzole | Zendy

Hilpert Hans | Zendy; Hoesch Lienhard | Zendy; Dreiding André S. | Zendy

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Die Produkte der Thermolyse von N ‐(1‐Pyridinio)‐2‐nitroaniliden sind keine Triaziridine, sondern 1, 2‐Bis[(2′‐nitrophenyl)‐azoxyl]‐benzole

Author(s) -

Hilpert Hans,

Hoesch Lienhard,

Dreiding André S.

Publication year - 1981

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19810640715

Subject(s) - chemistry , thermal decomposition , medicinal chemistry , azoxy , nuclear magnetic resonance spectroscopy , polymer chemistry , organic chemistry

The products of the thermolysis of N ‐(1‐pyridinio)‐2‐nitroanilides ( 1 ) had previously been interpreted as tris (2‐nitrophenyl)‐triaziridines ( 3 ). The present work shows them to be actually 1, 2‐bis[( Z )‐(2′‐nitrophenyl)‐ONN‐azoxy]benzenes ( 5 ). The revised structural assignment is based on the chemical and the spectroscopic (especially 1 H‐NMR.) properties of 5 and on the results of a X‐ray structural analysis.

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