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Notiz zum massenspektrometrischen Zerfall monohalogenierter Essigsäuren und Essigsäureester. 36. Mitteilung über massenspektrometrische Untersuchungen
Author(s) -
LorenziRiatsch Annalaura,
Bild Norbert,
Hesse Manfred
Publication year - 1981
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19810640534
Subject(s) - chemistry , fragmentation (computing) , mass spectrum , decomposition , ion , medicinal chemistry , organic chemistry , computer science , operating system
Note on the Mass Spectral Decomposition of Monohalogenated Acetic Acids and its Esters Besides the well known ester fragmentation reactions two unusual decomposition reactions are observed in the mass spectra of the title compounds, leading to the ions [ M ‐CO 2 ] + and [ M ‐HX] + . The rearrangement reactions involved in the formation of these ions are discussed.