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Bestimmung der Chiralität optisch aktiver Nickelkomplexe mit porphinoidem Ligandysystem
Author(s) -
Meier Kurt,
Scheffold Rolf,
Engel Peter
Publication year - 1981
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19810640525
Subject(s) - chemistry , chirality (physics) , optically active , stereochemistry , nickel , organic chemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
Determination of the Chirality of Optically Active Porphine Type Nickel Complexes The chirality of (+)‐[1‐methyl‐8 H‐HDP]nickelperchlorate ( 4 ) was determined to be (1 R ) by X‐ray analysis of 7a combined with chemical correlation of the chirality at C(1′) of the 1′‐methyl‐2′‐oxopropoxy side chain of 7a with (−)‐( R )‐2‐methyl‐2,3‐butandiol ( 9 ).