Partial Synthesis of 3′‐Hydroxy‐2′‐deoxy‐2″,3″,4″,5″‐tetrahydroverrucarin A. Verrucarins and roridins, 38th Communication [1] | Zendy

Notegen EricAndréa | Zendy; Tori Motoo | Zendy; Tamm Christoph | Zendy

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Partial Synthesis of 3′‐Hydroxy‐2′‐deoxy‐2″,3″,4″,5″‐tetrahydroverrucarin A. Verrucarins and roridins, 38th Communication [1]

Author(s) -

Notegen EricAndréa,

Tori Motoo,

Tamm Christoph

Publication year - 1981

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19810640132

Subject(s) - chemistry , sesquiterpene , adipic acid , derivative (finance) , terpene , stereochemistry , alcohol , trichothecene , butanone , organic chemistry , biochemistry , financial economics , economics , toxin , solvent

The macrocyclic trichothecene triester 3′‐hydroxy‐2′‐deoxy‐2",3",4",5"‐tetrahydroverrucarin A ( 37 ), has been synthesized starting from the sesquiterpene alcohol verrucarol ( 3 ), adipic acid and a derivative of mevalonic acid ( 14 ). The latter has been prepared from 4‐(tetrahydro‐2‐pyranyloxy)‐2‐butanone ( 9 ).

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