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A Stereoselective Approach to the Spiro [4, 5]decane System via Intramolecular Photocycloaddition and Reductive Fragmentation. Preliminary communication
Author(s) -
Oppolzer Wolfgang,
Gorrichon Liliane,
Bird T. Geoffrey C.
Publication year - 1981
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19810640120
Subject(s) - chemistry , decane , stereoselectivity , intramolecular force , fragmentation (computing) , stereochemistry , cleavage (geology) , medicinal chemistry , organic chemistry , catalysis , computer science , operating system , geotechnical engineering , fracture (geology) , engineering
Abstract The photoaddition 6 → 7 , followed by a reductive cleavage of the →‐chlorocyclobutylketone 7 , gave the stereochemically pure spiro [4,5]decane 8 .