Action du cyanure mercurique sur quelques halogénures de désoxy‐3‐trifluoroacétamido‐3‐ D ‐ribofurannosyle. Note de laboratoire | Zendy

Tronchet par Jean M. J. | Zendy; Grouiller Annie | Zendy; Martin Olivier R. | Zendy

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Action du cyanure mercurique sur quelques halogénures de désoxy‐3‐trifluoroacétamido‐3‐ D ‐ribofurannosyle. Note de laboratoire

Author(s) -

Tronchet par Jean M. J.,

Grouiller Annie,

Martin Olivier R.

Publication year - 1980

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19800630814

Subject(s) - chemistry , halide , bromide , cyanide , medicinal chemistry , derivative (finance) , inorganic chemistry , financial economics , economics

Reactions of Some 3‐Deoxy‐3‐trifluoroacetamido‐ D ‐ribofuranosyl Halides with Mercuric Cyanide The expected 2,5‐anhydro‐ D ‐allononitrile 11 was obtained when the 2‐ O ‐benzoyl‐3‐deoxy‐3‐trifluoroacetamido‐ D ‐ribofuranosyl bromide reacted with mercuric cyanide, whereas the isomeric 1,2‐ O (1‐cyanoethylidene) derivative was formed from the 2‐ O ‐acetylated halide; no reaction occurred when the halide was 2‐ O‐p ‐nitrobenzoylated.

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