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Action du cyanure mercurique sur quelques halogénures de désoxy‐3‐trifluoroacétamido‐3‐ D ‐ribofurannosyle. Note de laboratoire
Author(s) -
Tronchet par Jean M. J.,
Grouiller Annie,
Martin Olivier R.
Publication year - 1980
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19800630814
Subject(s) - chemistry , halide , bromide , cyanide , medicinal chemistry , derivative (finance) , inorganic chemistry , financial economics , economics
Reactions of Some 3‐Deoxy‐3‐trifluoroacetamido‐ D ‐ribofuranosyl Halides with Mercuric Cyanide The expected 2,5‐anhydro‐ D ‐allononitrile 11 was obtained when the 2‐ O ‐benzoyl‐3‐deoxy‐3‐trifluoroacetamido‐ D ‐ribofuranosyl bromide reacted with mercuric cyanide, whereas the isomeric 1,2‐ O (1‐cyanoethylidene) derivative was formed from the 2‐ O ‐acetylated halide; no reaction occurred when the halide was 2‐ O‐p ‐nitrobenzoylated.