Premium
Isomerisierung der Bis(triphenylphosphin)platin(0)‐Komplexe von Bicyclo[4.2.1]non‐1‐en und Bicyclo[4.2.1]non‐1(8)‐en
Author(s) -
Stamm Erich,
Becker Konrad B.,
Engel Peter,
Keese Reinhart
Publication year - 1979
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19790620715
Subject(s) - bicyclic molecule , chemistry , triphenylphosphine , isomerization , medicinal chemistry , ethylene , catalysis , organic chemistry
Isomerization of the Bis(triphenylphosphine)platin(0) Complexes of Bicyclo[4.2.1]non‐1‐ene and Bicyclo[4.2.1]non‐1(8)‐ene Isomrisation of the Bredt ‐Olefins 3 and 7 as the bis (triphenylphosphine)‐Pt(0) complexes 1 and 8 , respectively, has been observed. The bridgehead‐olefin 3 as well as the bicyclic olefins 4 , 5 and 6 have also been isomerized with catalytical amounts of (ethylene)bis(triphenylphosphine)platinum(0) ( 2 ).