Isomerisierung der Bis(triphenylphosphin)platin(0)‐Komplexe von Bicyclo[4.2.1]non‐1‐en und Bicyclo[4.2.1]non‐1(8)‐en | Zendy

Stamm Erich | Zendy; Becker Konrad B. | Zendy; Engel Peter | Zendy; Keese Reinhart | Zendy

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Isomerisierung der Bis(triphenylphosphin)platin(0)‐Komplexe von Bicyclo[4.2.1]non‐1‐en und Bicyclo[4.2.1]non‐1(8)‐en

Author(s) -

Stamm Erich,

Becker Konrad B.,

Engel Peter,

Keese Reinhart

Publication year - 1979

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19790620715

Subject(s) - bicyclic molecule , chemistry , triphenylphosphine , isomerization , medicinal chemistry , ethylene , catalysis , organic chemistry

Isomerization of the Bis(triphenylphosphine)platin(0) Complexes of Bicyclo[4.2.1]non‐1‐ene and Bicyclo[4.2.1]non‐1(8)‐ene Isomrisation of the Bredt ‐Olefins 3 and 7 as the bis (triphenylphosphine)‐Pt(0) complexes 1 and 8 , respectively, has been observed. The bridgehead‐olefin 3 as well as the bicyclic olefins 4 , 5 and 6 have also been isomerized with catalytical amounts of (ethylene)bis(triphenylphosphine)platinum(0) ( 2 ).

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