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Rhodium‐Catalyzed Deuterioformylation of 3‐Methyl‐1‐pentene
Author(s) -
Stefani Annibale,
Tatone Dante,
Pino Piero
Publication year - 1979
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19790620419
Subject(s) - chemistry , rhodium , pentene , enantiomer , diastereomer , catalysis , olefin fiber , stereochemistry , medicinal chemistry , organic chemistry
3‐Methyl‐1‐pentene was deuterioformylated in the presence of rhodium‐catalyst. The extent of attack on each face of the olefin was evaluated from the diastereomeric composition of both positional isomers obtained as the products. An overall preferred attack on the si‐si face of the ( S )‐enantiomer, and on the re‐re face of the ( R )‐enantiomer was found.