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Hydroxid‐bewirkte Halogenwasserstoff‐Abspaltungen aus vic ‐Dihalogeniden unter heterogenen Bedingungen: Reaktionssteuerung dank überraschender Solvens‐ und Metall‐Einflüsse
Author(s) -
Tarchini Claudio,
An Tran Dinh,
Jan Gérald,
Schlosser Manfred
Publication year - 1979
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19790620230
Subject(s) - chemistry , dehydrohalogenation , sodium hydroxide , potassium hydroxide , halide , solvent , hydroxide , halocarbon , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Hydroxide‐Promoted Dehydrohalogenation of vic ‐Dihalides under Heterogeneous Conditions: Control Over the Reaction Outcome Due to Surprising Solvent and Metal Effects Selective elimination of either one or two molecules of hydrogen halide from vic ‐dihalides can be conveniently achieved by employing solid sodium or potassium hydroxide in the presence of solvents such as glycol dimethylether or tetraethyleneglycol dimethylether.