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Syntheses and Absolute Configuration of ( E )‐ and ( Z )‐α‐Bisabolenes
Author(s) -
Delay Franç,
Ohloff Günther
Publication year - 1979
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19790620203
Subject(s) - chemistry , stereospecificity , absolute configuration , stereochemistry , absolute (philosophy) , nuclear magnetic resonance spectroscopy , organic chemistry , catalysis , philosophy , epistemology
Stereospecific syntheses of ( E )‐ and ( Z )‐α‐bisabolenes have made revision of the configuration of natural (+)‐α‐bisabolene from Opoponax oil necessary. 13 C‐NMR. spectroscopy has been used for the differentiation of these isomers.